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On equilibrium distributions and detailed balance relations in non-isothermal systems

✍ Scribed by A. Ben-Shaul; M. Tabor

Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
565 KB
Volume
61
Category
Article
ISSN
0009-2614

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✦ Synopsis

The signitiunce of the detailed balance principle and equilibrium solutions of the master equation is discussed from a thermodynamic point of view for isohted and isorhermai systems. Starting from e master equation for aII the time dependent degrees of freedom it is shown that the uniquenessof the equilibrium distribution as a stationary solution is ensured if the detailed rate constants are Manced with the aid of the distribution which maximizes the entropy subject to the thermodynamic constmiutr This procedure should precede physical assumptions which simplify the origimd master equation, e-g-the assumption that rapidly reboxing modes can be described by canomal distribution functions.

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