On electrochemical behaviour of zinc in organic solvents
✍ Scribed by S. Bia&ł;&ł;ozór; E.T. Bandura
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 326 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0013-4686
No coin nor oath required. For personal study only.
✦ Synopsis
The electrochemical behaviour of Zn has been investigated in DMSO, DMF and AN by potentiostatic and voltammetric methods. The values of pm and fin equal to 0.5 and 1 show that the charge-discharge of Zn z l in these solvents proceeds as a two-step reaction. The values of apparent exchange current densities depend on the employed measurement techniques. The assumption about the passivation of Zn electrode by the products of secondary chemical reaction has been formulated.
📜 SIMILAR VOLUMES
Requirements for the degree of exclusion of water of the so-called non-aqueous electrolytes depend largely on the electrochemical systems under consideration and there is therefore no unique definition with regard to limits. The electrochemistry of alkali metals is understandably extremely sensitive
Vitamin B 12 enzymes, involving the cobalt species as a catalytic center, mediate various isomerization reactions accompanied by carbon-skeleton rearrangements. In order to simulate the catalytic functions of vitamin B 12 as exerted in the hydrophobic active sites of enzymes concerned, we have been