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On computationally adjusting the Hill equation of adsorption

✍ Scribed by Joaquin Cortés; Heinrich Puschmann; Eliana Valencia

Publisher
John Wiley and Sons
Year
1984
Tongue
English
Weight
708 KB
Volume
5
Category
Article
ISSN
0192-8651

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✦ Synopsis

We discuss the implementation and computational efficiency of one approach to adjusting the Hill equation of adsorption to a set of empirical data, pointing out some aspects that seem to be valid in the general case. The approach consists basically of minimizing squares of deviations of the adsorbed amounts, which are numerically computed in terms of the empirical pressures and the parameters. Hill's equation is dealt with as a prototype of nonlinear equations seldom used by chemists because none of their variables can be set free.

📜 SIMILAR VOLUMES

On the Floquet Exponents of Hill's Equat
On the Floquet Exponents of Hill's Equation Systems
✍ Robert Denk 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 292 KB 👁 1 views

For the k x k-matrix-valued version of Hill's equation it is shown that the dimension of the matrix needed to compute the Floquet exponents can be reduced from 2k to k. Also the existence of periodic solutions is equivalent to the non-invertibility of certain k x k-matrices.