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On catalyzed and uncatalyzed hydroborations of chiral allylic alcohols and amines

โœ Scribed by Kevin Burgess; Michael J. Ohlmeyer

Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
232 KB
Volume
30
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

A model for predicting the sense of diastereoselection in catalyzed hydroborations 01 allylic alcohol and allylic amine derivatives is discussed.

๐Ÿ“œ SIMILAR VOLUMES

Substrate-controlled diastereoselectivit
Substrate-controlled diastereoselectivity in catalyzed and uncatalyzed hydroborations of allylic amine derivatives
โœ Kevin Burgess; Michael J. Ohlmeyer ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 256 KB

Hydroboration of the protected, homochiral allylic amines ( 6) -( 10) with 9-BBN, and with catecholborane/modium catalyst, give different stereoselectivities; the catalyzed reactions provide access to syn-3amino-2-methyl alcohols ( 11) -( 15).

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Pdร—Et3B-Catalyzed Alkylation of Amines with Allylic Alcohols.
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## Abstract For Abstract see ChemInform Abstract in Full Text.