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On a possible role of intersite correlations and crystal structure in determining the valence in mixed valence compounds

โœ Scribed by D.I. Khomskii


Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
385 KB
Volume
50
Category
Article
ISSN
0038-1098

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The electronic (350-900 nm), infrared and Raman (700-30 cm-1) spectra of polycrystalline samples of the mixedvalence (Ce3'/Ce4') oxysulรde compound were investigated. The compound is a low-gap semiconductor Ce 4 O 4 S 3 with intervalence transitions in the near-infrared (ca. 850 nm) and visible (ca.