A diagammatic,interprct~tion of the formal (i.e.; without second quantization ~ormalismj quasi-degenerate Rayleigh-Sciuiidinger perturbation theory with non-hem+ian model hamiltonian is suggested. fn this appro&. : the diagrammatic expressions for the Bloch wave operator U as well as for the model
On a formal treatment of the Rayleigh-Schrödinger perturbation theory
✍ Scribed by Dietrich Haase
- Publisher
- Springer
- Year
- 1978
- Tongue
- English
- Weight
- 589 KB
- Volume
- 49
- Category
- Article
- ISSN
- 1432-2234
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## Abstract Several useful “redefined zero‐order Hamiltonian” variants of the Rayleigh–Schrödinger perturbation theory are derived by exploiting the freedom of choice for the orthogonality integral between zero‐ and first‐order wavefunctions. It is found that the more common Hamiltonian repartition