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On a class of extended mean spherical approximations

✍ Scribed by Magdaleno Medina Noyola; Donald A. McQuarrie; Wilmer Olivares


Publisher
Elsevier Science
Year
1978
Tongue
English
Weight
370 KB
Volume
58
Category
Article
ISSN
0009-2614

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✦ Synopsis


The extended mean spherical appro-ximation of Martina B. and de1 Rio is solved variationaBy for the restricted primitive model of l-l and 2-2 eIectrolyte solutions Thermodynamic properties are cakulated and compared to Monte Carlo results for the same modeL A modification of the extended mean spherical approximation is presented that is more internally se&consistent and is in better agreement with Monte Carlo data.


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Analytic solution of the mean spherical
✍ M. Parrinello; M.P. Tosi πŸ“‚ Article πŸ“… 1979 πŸ› Elsevier Science 🌐 English βš– 217 KB

Tile mean spheriul approximation for a mi..ture of charged hard spheres in a uniform neutralizing background is solved anaIyticzlly\_ The factor correlation functions and the excess thermodynamic properties are explicitly expressed through a single parameter, which can be obtained by solving an alge