On a class of extended mean spherical approximations
β Scribed by Magdaleno Medina Noyola; Donald A. McQuarrie; Wilmer Olivares
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- English
- Weight
- 370 KB
- Volume
- 58
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
β¦ Synopsis
The extended mean spherical appro-ximation of Martina B. and de1 Rio is solved variationaBy for the restricted primitive model of l-l and 2-2 eIectrolyte solutions Thermodynamic properties are cakulated and compared to Monte Carlo results for the same modeL A modification of the extended mean spherical approximation is presented that is more internally se&consistent and is in better agreement with Monte Carlo data.
π SIMILAR VOLUMES
Tile mean spheriul approximation for a mi..ture of charged hard spheres in a uniform neutralizing background is solved anaIyticzlly\_ The factor correlation functions and the excess thermodynamic properties are explicitly expressed through a single parameter, which can be obtained by solving an alge