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Oligothiophene-Based Catenanes: Synthesis and Electronic Properties of a Novel Conjugated Topological Structure

✍ Scribed by Peter Bäuerle; Martin Ammann; Markus Wilde; Günther Götz; Elena Mena-Osteritz; Alexander Rang; Christoph A. Schalley


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
439 KB
Volume
119
Category
Article
ISSN
0044-8249

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The synthesis of a topologically chiral in,out-bis-sulfonamide catenane and its "dimer" are reported. The structures of the amide wheel and of the catenane were resolved by X-ray analysis. NMR-titration of the monosulfonamide-wheel yielded conclusive association constants supporting the proposed reg