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Oligosaccharides from "standardized intermediates." Synthesis of a branched tetrasaccharide glycoside related to the blood group B determinant

✍ Scribed by Nashed, Mina A.; Anderson, Laurens


Book ID
126809407
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
696 KB
Volume
104
Category
Article
ISSN
0002-7863

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📜 SIMILAR VOLUMES


Oligosaccharides from “standardized inte
✍ Mina A. Nashed; Laurens Anderson 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 679 KB

Building block derivatives of the component monosaccharides were used to construct the tetrasaccharide glycoside 15, in which an alpha-D-Galp-(1 leads to 4)-D-Gal linkage replaces the alpha-(1 leads to 3) linkage of the human blood-group B, type 2, determinant structure. The initial coupling of 2-O-

Oligosaccharides from “standardized inte
✍ Mina A. Nashed; Laurens Anderson 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 598 KB

The selectively benzylated glycoside allyl 2-acetamido-4,6-di-O-benzyl-2-deoxy-beta-D-galactopranoside (4) was prepared from the corresponding derivative of 2-acetamido-2-deoxy-D-glucose via the p-bromobenzenesulfonate and the benzoate. 2-O-Benzoyl-3,4,6-tri-O-benzyl-alpha-D-galactopyranosyl (10) wa