Oligonuclear Copper Complexes of a Bioinspired Pyrazolate-Bridging Ligand: Synthesis, Structures, and Equilibria in Solution
โ Scribed by Prokofieva, Angelina; Prikhod'ko, Alexander I.; Enyedy, Eva Anna; Farkas, Etelka; Maringgele, Walter; Demeshko, Serhiy; Dechert, Sebastian; Meyer, Franc
- Book ID
- 118157889
- Publisher
- American Chemical Society
- Year
- 2007
- Tongue
- English
- Weight
- 355 KB
- Volume
- 46
- Category
- Article
- ISSN
- 0020-1669
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๐ SIMILAR VOLUMES
## Abstract A new binucleating bis(terdentate) ligand, 3,5โ[3โbis(2โpyridyl)pyrazoleโ1โylmethyl]pyrazole (HL^2^), was synthesized. Reaction of the deprotonated ligand L^2^ with hydrated Cu^II^ salts gives (ฮผโpyrazolato)(ฮผโhydroxido)โbridged binuclear and tetranuclear complexes [L^2^Cu~2~(ฮผโOH)(ClO~
## Basel (31.VII.97
A dinuclear Cu II complex [Cu 2 (bpp) 2 (H 2 O) 2 ](ClO 4 ) 2 (1) with 3,5-bis(2-pyridyl)pyrazole (Hbpp), has been synthesized and characterized by elemental analyses, thermal analysis, conductance, UV-vis and IR spectra. The crystal structure of 1, determined by X-ray diffraction technique, reveals