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Oligonuclear Copper Complexes of a Bioinspired Pyrazolate-Bridging Ligand: Synthesis, Structures, and Equilibria in Solution

โœ Scribed by Prokofieva, Angelina; Prikhod'ko, Alexander I.; Enyedy, Eva Anna; Farkas, Etelka; Maringgele, Walter; Demeshko, Serhiy; Dechert, Sebastian; Meyer, Franc


Book ID
118157889
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
355 KB
Volume
46
Category
Article
ISSN
0020-1669

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## Abstract A new binucleating bis(terdentate) ligand, 3,5โ€[3โ€bis(2โ€pyridyl)pyrazoleโ€1โ€ylmethyl]pyrazole (HL^2^), was synthesized. Reaction of the deprotonated ligand L^2^ with hydrated Cu^II^ salts gives (ฮผโ€pyrazolato)(ฮผโ€hydroxido)โ€bridged binuclear and tetranuclear complexes [L^2^Cu~2~(ฮผโ€OH)(ClO~

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A dinuclear Cu II complex [Cu 2 (bpp) 2 (H 2 O) 2 ](ClO 4 ) 2 (1) with 3,5-bis(2-pyridyl)pyrazole (Hbpp), has been synthesized and characterized by elemental analyses, thermal analysis, conductance, UV-vis and IR spectra. The crystal structure of 1, determined by X-ray diffraction technique, reveals