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Oligomerization of benzylic alcohols and its mechanism

✍ Scribed by Raymundo Cruz-Almanza; Izumi Shiba-Matzumoto; Aydee Fuentes; Marcos Martínez; Armando Cabrera; Jorge Cárdenas; Manuel Salmón

Book ID
104423494
Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
678 KB
Volume
126
Category
Article
ISSN
1381-1169

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Permanganate, solubilized in methylene chloride with the aid of a phase transfer agent, oxidizes benzyl alcohol to benzaldehyde and bcnzyl ethers to benzoate esters. Although the rate of oxidation of the ether is about an order of magnitude slower than alcohol oxidation, both respond in an identical