Olefin π-complex formation and kinetics of oxidative dimerisation in the palladium(II) acetate system
✍ Scribed by A.K. Yatsimirsky; A.D. Ryabov; I.V. Berezin
- Publisher
- Elsevier Science
- Year
- 1978
- Weight
- 762 KB
- Volume
- 4
- Category
- Article
- ISSN
- 0304-5102
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The oxidative addition of the allylic acetate, CH 2 CH À CH 2 À OAc, to the palladium(0) complex [Pd 0 (P,P)], generated from the reaction of [Pd(dba) 2 ] with one equivalent of P,P (P,P dppb 1,4-bis(diphenylphosphanyl)butane, and P,P dppf 1,1'-bis(diphenylphosphanyl)ferrocene), gives a cationic (h
In the absence of CuC12, ethene was oxidized to ethanal by PdCl,(pyridine) -in aqueous solution by the rate expression: \* where K' is the equilibrium constant for n-complex formation between ethene and PdCl,(Py) -(Py =pyridine). This rate expression is of the same form as that previously found for