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Olefin polymerization with Me4Cp–Amido complexes with electron-withdrawing groups

✍ Scribed by Masami Kamigaito; Tapan K. Lal; Robert M. Waymouth

Book ID
101348500
Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
216 KB
Volume
38
Category
Article
ISSN
0887-624X

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✍ Xiaoxia Yang; Yong Zhang; Jiling Huang 📂 Article 📅 2006 🏛 Elsevier Science 🌐 English ⚖ 280 KB

The new ansa-complexes (R-Ph) 2 C(Cp)(Ind)MCl 2 (R = CF 3 , F, Cl; M = Ti, Zr or Hf) were synthesized from the reaction of dilithium salt of the corresponding ligands with appropriate group 4 metal halides. They were tested for ethylene homopolymerization and copolymerization in the presence of meth