Olefin polymerization catalyzed by homoor heterobimetallic zirconocene complex/methylaluminoxane system
β Scribed by Makoto Mitani; Kunihiro Oouchi; Michiya Hayakawa; Tohru Yamada; Teruaki Mukaiyama
- Book ID
- 104709384
- Publisher
- Springer
- Year
- 1995
- Tongue
- English
- Weight
- 288 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0170-0839
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π SIMILAR VOLUMES
{[2-(dimethylamino) ethyl]cyclopentadienyl}titanium trichloride (Cp N TiCl 3 , 1) was activated with methylaluminoxane (MAO) to catalyze polymerizations of ethylene (E), propylene (P), ethylidene norbornene (ENB), vinylcyclohexene (VCH), and 1,4-hexadiene (HD). The dependence of homopolymerization
DFT (density-functional theory) calculations were performed to investigate the thermodynamics of formation of Olefin Separated Ion Pairs (OSIP) Cp2MtCH~/C2H4/Cl2AI[O(A1Me3)AlHMe]; (Cp = q5-C5H5, Mt = Ti, Zr, Me = CH3) from ethylene and Cp2MtMe \* C12AI[O(AlMe3)A1HMe]2, a model of adduct produced by