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Olefin metathesis in polycyclic frames 1. A new way to cis, syn, cis - tricyclopentanoids (acs-C11-triquinanes)

✍ Scribed by Goverdhan Mehta; A.Veera Reddy; A. Srikrishna

Publisher: Elsevier Science
Year: 1979
Tongue: French
Weight: 214 KB
Volume: 20
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)86734-4

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✦ Synopsis

A novel olefin metathesis sequence permits ready access to functionalised s, syp, cis-tricycle r6.3.0.0 2,6 --] undecane based bis-enones. These bis-enones have been shown to undergo

cage cyclisation in sunlight with remarkable ease and efficiency.

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A general synthetic approach to cis, syn

A general synthetic approach to cis, syn, cis- triquinanes via reductive carbon-carbon bond cleavage in polycyclic frames: Strategy for bis-cyclopentane annulation of 1,3-cyclopentadiene

✍ Goverdhan Mehta; Kotha Sambasiva Rao 📂 Article 📅 1983 🏛 Elsevier Science 🌐 French ⚖ 214 KB

A short, general and flexible approach to c&, z, cis-tricyclo(6.3.0.0 2r6)undecane 4,10-dione and its derivatives from abundantly available pentacyclo (5.4.0.0 2'6.03'10.05'g)undecane-8,11-diones is described.