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Olefin isomerization reactions catalyzed by ruthenium hydrides bearing Schiff base ligands

โœ Scribed by Fu Ding; Sabine Van Doorslaer; Peggie Cool; Francis Verpoort


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
173 KB
Volume
25
Category
Article
ISSN
0268-2605

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Radical reactions catalysed by homobimet
โœ Bob De Clercq; Francis Verpoort ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 191 KB

The homobimetallic ruthenium Schiff base complexes Ia-f mediated the atom transfer radical addition (ATRA) of carbon tetrachloride across olefins in excellent yields which markedly depended on the catalyst and the substrate used. The best catalytic system Ic is able to compete with the highest perfo