Radical reactions catalysed by homobimet
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Bob De Clercq; Francis Verpoort
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Article
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2002
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Elsevier Science
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French
โ 191 KB
The homobimetallic ruthenium Schiff base complexes Ia-f mediated the atom transfer radical addition (ATRA) of carbon tetrachloride across olefins in excellent yields which markedly depended on the catalyst and the substrate used. The best catalytic system Ic is able to compete with the highest perfo