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Olefin complexes of divalent ruthenium formed by chelating olefinic tertiary phosphines and arsines

โœ Scribed by Bennett, M. A.; Johnson, R. N.; Tomkins, I. B.


Book ID
127396040
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
654 KB
Volume
13
Category
Article
ISSN
0020-1669

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On the existence of dioxygen adducts of
โœ B.R. James; L.D. Markham; A.D. Rattray; D.K.W. Wang ๐Ÿ“‚ Article ๐Ÿ“… 1976 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 168 KB

The reported [3] I: 1 O2 absorption by RuC12-(AsPh& must be due to oxidation of 2 mol of coordinated arsine in complexes such as those listed above. The so-called 880 cm-' peroxide band is attributable to VA-, and the paramagnetism and esr signals (assigned to a Ru"'-O; moiety) are likely due to Ru(