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Old Clusters with New Tricks: Engineering S⋅⋅⋅S Interactions and Novel Physical Properties in Sulfite-Based Dawson Clusters

✍ Scribed by De-Liang Long; Paul Kögerler; Leroy Cronin

Book ID: 101560235
Publisher: John Wiley and Sons
Year: 2004
Tongue: English
Weight: 151 KB
Volume: 43
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.200352896

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Zwei pyramidale Sulfitionen wirken als Template bei der Bildung neuer 18‐Molybdosulfit‐Dawson‐Cluster. Die Wechselwirkung zwischen den beiden SO~3~^2−^‐Ionen wurde mit DFT‐Rechnungen untersucht. Das [Mo~18~O~54~(SO~3~)~2~]^4−^‐Ion ist das erste diskrete thermochrome Polyoxometallat: Es ändert seine