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OH/OD bond breaking selectivity in hod photodissociation

โœ Scribed by Jinzhong Zhang; Dan G. Imre

Book ID
103028247
Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
483 KB
Volume
149
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

The OH/OD bond breaking selectivity in HOD photodissociation is studied on the first excited state using a quantum-mechanical time-dependent technique. A simple two-photon scheme is presented to produce pure OD t H. The first photon prepares vibrationally excited HOD; the second, a UV photon, excites the molecule to the dissociative A state. The selectivity in bond breaking is over a large frequency region where no other present species absorb.

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