✦ LIBER ✦
OH (A 2Σ+) fragment emission from reaction of electronically excited Xe(6p) with H2O under free jet and bulb conditions
✍ Scribed by Satoshi Hashimoto; Yutaka Matsumi; Masahiro Kawasaki
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 588 KB
- Volume
- 200
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
The state-selective energy transfer from two-photon excited Xe(6p) to Hz0 and the subsequent reaction has been studied by measurement of emission spectra of OH(A*Z' +X *II). The vibrational population ratios, N_,/N,=,, are 0.52 +O.Ol in a free jet and 0.37 kO.02 in a bulb. This reveals the difference in dissociation dynamics following the intra-complex and the intermolecular electronic energy transfers from Xe(6p) to H,O.