Molecular octopole moments are rigorously calculated using two different semi,empirical wavefunctions. The resuits are compared with ab initio calculations and experimental data where available. IEHT wavefunctions are found to give a reasonable representation of multipole moments up to octopole.
Octopole moment of CH3D
β Scribed by G.D.T. Tejwani; K. Fox
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- English
- Weight
- 293 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
β¦ Synopsis
The magnitude of an effective octopole moment of CH3D has been obtained as QCH,D = (5.6 f 1.5) X !O-34 esu cm3 by a comparison of calculated and measured values of self-broadened linewidths for J= 6 -+ 7 transitions in ?he pure rotational spectrum of this molecule.
π SIMILAR VOLUMES
The microwave spectrum of \(\left(\mathrm{CF}_{3}\right)_{3} \mathrm{CCCH}\) has been recorded on the NIST Fourier-transform microwave spectrometer. The rotational constant for the principal isotopomer is found to be \(B_{0}\) \(=690.87916\) (4) \(\mathrm{MHz}\) and the dipole moment \(\mu_{0}=2.038
This article describes the concept, design, implementation, and preliminary classroom experience of a computer-based, three-dimensional simulator for moments of inertia of uniform solid bodies. Rotation angles about each of three Cartesian axes are user-adjustable. The moment of inertia tensor is up