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Octanuclear Bis(triple-helical) Metal(II) Complexes

✍ Scribed by Rolf W. Saalfrank; Norbert Löw; Stefan Trummer; George M. Sheldrick; Markus Teichert; Dietmar Stalke


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
207 KB
Volume
1998
Category
Article
ISSN
1434-1948

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The ligand neopentyl 2,6-bis[(1-methylbenzimidazol-2-yl)]pyridine-4-carboxylate (L 12 ) has been synthesised to test the effect of the chiral neopentyl ester group in the 4-position of the pyridine ring on (i) the helical wrapping, (ii) the diastereomeric induction and (iii) the thermodynamic and ph