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Octafluorobicyclo[2.2.0]hex-1(4)-ene: A Greatly Strained Alkene with Novel Reactivity

โœ Scribed by Zhang, Yin; Smith, Joshua; Lemal, David M.


Book ID
126969602
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
148 KB
Volume
118
Category
Article
ISSN
0002-7863

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Molecular oxygen trapping reaction of alkenes with 2,3-pyrrolidinedione derivatives was developed using a Mn(lll)-induced oxidation system. AIkenes and 2,3-pyrrolidinediones were treated with manganese(Ill) acetate in acetic acid under a stream of dry air, giving l-hydroxy-8-aza-2,3-dioxabicyclo[4.3