Photochemistry of the isocyanatopentaamm
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Abbas A. El-Awady; Fred Basolo
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Article
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1978
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Elsevier Science
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English
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## Photochemical studies of azido metal complexes of the type [M(NH,)sN,12', where M = Ir(III) and Rh(III) suggest the decomposition of the azido group via a coordinated nitrene intermediate [l-3]. The Ir(III) complex [4] and the corresponding Ru(III) complex [S] also react thermally with acid by