Observations on the allylic bromination of some bridged polycyclic olefins

✍ Scribed by D.I. Davies; L.T. Parfitt

• Book ID: 104239002
• Publisher: Elsevier Science
• Year: 1969
• Tongue: French
• Weight: 189 KB
• Volume: 10
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(01)87674-7

✦ Synopsis

The benzoyl peroxide catalysed reactlon of N-bromosuccinimide, in boiling carbon tetrachloride, with 2-methylenebicyclol2,2,2loctane (I) affords an oil, g.1.c. examination of which shows one major peak (-85 $), and several minor peaks.

N.m.r. examlnatlon shows that the major peak