Observation of Three Intervalence-Transfer Bands for a Class II–III Mixed-Valence Complex of Ruthenium
✍ Scribed by Reginaldo C. Rocha; Francisca N. Rein; Hershel Jude; Andrew P. Shreve; Javier J. Concepcion; Thomas J. Meyer
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 453 KB
- Volume
- 120
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
A three-site model for bridged tied-valence dimersis discussed. Adiabatic potential energy surfaces which depend upon the vibrational sum and difference coordinates are obtained. Intensities of the vibronic transitions which contribute to the intervalence transfer band shape are calculated using pop
The first example of the determination of the electron transfer rate (k, V , DG Ã , k th ) for N ,N 0 -diphenyl-1,4-phenylenediamine derivatives using the Marcus-Hush theory is described. These results were in good agreement with the ones obtained using variable-temperature IR spectra measurements.
Pulsed laser resonance Raman (RR) studies of mono-and bi-nuclear complexes of Cu (1) with the bridging ligand 2,3-di-(2pyridyl)quinoxaline (dpq) and triphenyl phosphine (Ph,P) are reported. Laser flash photolysis at 416 nm or 532 nm in CHCI3 solution ofthe mononuclear complex, [ (Ph,P),Cu(dpq)]' (1)