The observation of a new ion-pair state of ICI, the H' 1 ( 'D2), is reported. Existing vibrational constants for the Gl (sP,) and p 1 ( 'P, ) states have been extended to cover the range u' = O-63 and v' =O-I 37 respectively. ## 1. Introdoction In two recent papers [ 1,2], we have shown how double
Observation of the f′0+(1D2) ion-pair state of ICl using double-resonance ionisation nozzle-cooled spectroscopy
✍ Scribed by R.J. Donovan; K.P. Lawley; T. Ridley; P.J. Wilson
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 239 KB
- Volume
- 207
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
The observation of a new ion-pair state of ICI, the fO+ ( ' D2) state, is reported. Dunham coefficients valid up to u' =28 have been determined.
Intxoduction
📜 SIMILAR VOLUMES
The \(0_{g}^{+}\left({ }^{1} D\right)\) ion-pair state of \(\mathrm{I}_{2}\) has been analyzed by optical-optical double-resonance using the \(0_{g}^{+}\left({ }^{1} D\right)-B^{3} \Pi\left(0_{u}^{+}\right)-X^{1} \Sigma_{g}^{+}\)photoexcitation sequence. The analysis of the 374 transitions in the \(
We have reinvestigated the \(0_{u}^{+}\left({ }^{3} P_{0}\right)\) ion-pair state of \(\mathrm{Cl}_{2}\) correlating to \(\mathrm{Cl}^{-}\left({ }^{1} S\right)+\mathrm{Cl}^{+}\left({ }^{3} P_{0}\right)\) by optical-optical double resonance. The \(\mathrm{Cl}_{2}\) molecules in the \(X^{1} \Sigma_{g}
The optical-optical double-resonance spectroscopy is applied to study the ion-pair states of \(\mathrm{Cl}_{2}\) correlating to \(\mathrm{Cl}^{-}\left({ }^{1} S\right)+\mathrm{Cl}^{+}\left({ }^{3} P_{2}\right)\). In the \((1+2)\) photoexcitation sequence, we gain access to the \(0_{u}^{+}\left({ }^{