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Observation of surface phonons on the (001) and (100) surfaces of anatase minerals

✍ Scribed by G. Durinck; H. Poelman; P. Clauws; L. Fiermans; J. Vennik; G. Dalmai


Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
233 KB
Volume
80
Category
Article
ISSN
0038-1098

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We present a comprehensive analysis of the Raman spectra of pure and zirconium-doped anatase TiO 2 nanoparticles. To account for the wavenumber shifts of the E g (Ξ½ 6 ) mode as a function of particle size (L) and dopant concentration (x), a modification of the standard phonon confinement model (PCM)