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Observation of non-equilibrium effects in free-convective flows using cars: Recirculating flow relaxation spectrometry

✍ Scribed by I.S. Dring; R. Devonshire; J. Meads; H.F. Boysan; D.A. Greenhalgh


Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
717 KB
Volume
132
Category
Article
ISSN
0009-2614

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✦ Synopsis


A stationary spatial distribution of non-equilibrium between the vibrational and the rotational/translational modes of Nz was established in the free-convective flows generated in a cylindrical cell by an axial, horizontal, incandescent filament. The non-equilibrium was detected and mapped using coherent anti-Stokes Raman scattering. The investigation illustrates a new approach to the study of high-temperature chemical kinetics and gas-phase transport properties called recirculating flow relaxation spectrometry.

It also highlights conditions where errors may arise in thermometry based on the spectroscopy of N2.