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Observation of Intramolecular CH⋅⋅⋅FC Contacts in Non-Metallocene Polyolefin Catalysts: Model for Weak Attractive Interactions between Polymer Chain and Noninnocent Ligand

✍ Scribed by Steven C. F. Kui; Nianyong Zhu; Michael C. W. Chan


Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
137 KB
Volume
115
Category
Article
ISSN
0044-8249

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## Abstract A family of Group 4 post‐metallocene catalysts, supported by fluorine‐functionalized tridentate ligands with the fluorine substituent in the locality of the metal center, is described. For the first time, the contentious CH⋅⋅⋅FC interaction has been characterized by a neutron diffract