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OBSERVATION OF C-S BOND CLEAVAGE IN THE PHOTOLYSIS OF A 2-AMINO-Δ2-THIAZOLINE DERIVATIVE

✍ Scribed by A. CORVAL; D. Gaude; P. Jardon; R. Gautron

Book ID
114893986
Publisher
John Wiley and Sons
Year
1982
Tongue
English
Weight
187 KB
Volume
36
Category
Article
ISSN
0031-8655

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Treatment of I-amino-2'-nitrobenzylphosphonic acids with aqueous sodium hydroxide caused a C-P bond cleavage, with formation of 3-amino-2,l-benzisoxazole derivatives (3). The leaving phosphorus moiety was identified here as phosphoric acid. In the case of basic hydrolysis of corresponding esters, ne