Observation and interpretation of low energy bands in the solution absorption spectra of Bk3+ and Bk4+
β Scribed by W.T Carnall; R.K Sjoblom; R.F Barnes; P.R Fields
- Publisher
- Elsevier Science
- Year
- 1971
- Weight
- 223 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0020-1650
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Christian Reichardt And Thomas Welton. Includes Bibliographical References (p. [587]-673) And Index.
Vibrational absorption and circular dichroism intensities due to the C-H stretching vibrations of 2,3-d+xiranc are interpreted by deriving semi-classical expressions involving the charge reorganization.
The interaction energy between dipole moments of electronic transitions in the monomers and the shape of absorption bands of organic dimers are calculated by the CNDO/S-CI method. It is found that the through-space resonance interaction between ~r orbitals of the monomers has a strong effect on the