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o -(Trifluoromethyl)aryl Interactions and Stabilization in Hypervalent Germanium Compounds

✍ Scribed by Bender, ; Banaszak Holl, Mark M.; Mitchell, Amy; Wells, Norman J.; Kampf, Jeff W.

Book ID
125973228
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
173 KB
Volume
17
Category
Article
ISSN
0276-7333

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✍ Ahlemann, Jens-T. ;Roesky, Herbert W. ;Murugavel, Ramaswamy ;Parisini, Emilio ;N πŸ“‚ Article πŸ“… 1997 πŸ› Wiley (John Wiley & Sons) 🌐 English βš– 934 KB

The reactions of potassium Rf-amide [R, = tris(trifluor0methyl)phenyl] (2) with PCl,, AsC13, and GeC1, 'dioxane yield new four-membered inorganic heterocycles [R,NPCl], (3), [RfNAsC1], (4), and [RfNGeI2 (5), respectively. On the other hand, the reaction of Rf-amide 2 with two equivalents of RfPCla l