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O-silylated ketene acetal chemistry1; divinyloxysilane derivatives as novel and useful bifunctional protecting agents for h-acidic materials

✍ Scribed by Yasuyuki Kita; Hitoshi Yasuda; Yoshio Sugiyama; Fumio Fukata; Jun-ichi Haruta; Yasumitsu Tamura


Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
290 KB
Volume
24
Category
Article
ISSN
0040-4039

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✦ Synopsis


Novel reagents, bis(l-methoxy-2-methyl-l-propenyloxy)silanes (2a-d) have been shown to be very useful bifunctional protecting agents for various types of H-acidic materials, such as diols, dithiols, diacids and their combined materials. The reaction proceeds rapidly under mild conditions to give the