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O-(E)-1-{1-[(6-Chloro­pyridin-3-yl)meth­yl]-5-methyl-1H-1,2,3-triazol-4-yl}ethyl­eneamino O-ethyl O-phenyl phospho­rothio­ate

✍ Scribed by Zhu, Xiao-Fei ;Shi, De-Qing

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
238 KB
Volume
62
Category
Article
ISSN
1600-5368

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O,O-Diethyl ({1-[(6-chloro­pyridin-3-yl)
O,O-Diethyl ({1-[(6-chloro­pyridin-3-yl)meth­yl]-5-methyl-1H-1,2,3-triazol-4-ylcarbon­yloxy}phen­yl­meth­yl)phospho­nate
✍ Chen, Xiao-Bao ;Shi, De-Qing 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 239 KB

In the title compound, C 21 H 24 ClN 4 O 5 P, the P atom adopts a distorted tetrahedral configuration. In the crystal structure, inter-and intramolecular C-HÁ Á ÁO hydrogen bonds contribute to the stability of the structure, andstacking interactions are also observed.

Ethyl 1-[(6-chloro­pyridin-3-yl)meth­yl]
Ethyl 1-[(6-chloro­pyridin-3-yl)meth­yl]-3-phenyl-1H-pyrazole-5-carboxyl­ate
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In the title compound, C 18 H 16 ClN 3 O 2 , the dihedral angles made by the pyrazole ring with the pyridine and phenyl rings are 82.43 (2) and 8.16 (3) , respectively. The crystal packing is stabilized mainly by van der Waals forces.

O,O-Diethyl [({1-[(2-chloro­thia­zol-5-y
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✍ Chen, Xiao-Bao ;Shi, De-Qing 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 232 KB

In the title compound, C 19 H 22 ClN 4 O 5 PS, the P atom adopts a distorted tetrahedral configuration. Intra-and intermolecular C-HÁ Á ÁO hydrogen bonds, together with weak C-HÁ Á Á hydrogen bonding and strongstacking interactions, stabilize the crystal structure.

Stereoselective synthesis and biological
Stereoselective synthesis and biological activities of O-(E)-1-{1-[(6-chloropyridin-3-yl)methyl]-5-methyl-1H-1,2,3-triazol-4-yl}ethyleneamino-O-ethyl-O-arylphosphorothioates
✍ Xiao-Fei Zhu; Xiao-Bao Chen; Man Yan; De-Qing Shi; Ke-Rong Ding 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 236 KB 👁 1 views

## Abstract To find novel lead compounds having high insecticidal activity, a series of phosphorothioate derivatives containing 1,2,3‐triazole and pyridine rings were synthesized by the reaction of 1‐{1‐[(6‐chloropyridin‐3‐yl)methyl]‐5‐methyl‐1H‐1,2,3‐triazol‐4‐yl}ethanone oxime with phosphorochlor

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✍ Chen, Xiao-Bao ;Shi, De-Qing 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 357 KB

In the title compound, C 14 H 16 ClN 7 O 2 , the triazole ring carries cyano and formamidine substituents and is bound via a methylene bridge to a chloropyridine unit. There is evidence of significant electron delocalization in the triazolyl system. Intramolecular O-HÁ Á ÁO and intermolecular C-HÁ Á