The diphenylmethyl group is introduced for the protection of the hydroxyl group of a-\_--\_\_\_ hydroxy acids.
O-diphenylmethylation of alcohols and carboxylic acids using diphenylmethyl diphenyl phosphate as alkylating agent
β Scribed by Miltiadis Kolovos; Cleanthis Froussios
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- French
- Weight
- 205 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
Diphenylmethyl diphenyl phosphate reacts quickly under mild conditions with various alcohols and carboxylic acids towards diphenylmethyl ethers and esters respectively while hydroxyacids can be selectively alkylated at the alcohol site.
π SIMILAR VOLUMES
A new convenient route to silyl ethers and esters from alcohols and carboxylic acids using allylsilanes in the presence of an acid catalyst in acetonitrile was developed. The present method is also applicable to t-butyldimethylsilylation. Trimethylsilyl group is the most versatile one for protectio
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v