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O (3P) + CH3SH reactions: Structures, energetics, and kinetics

✍ Scribed by Daniely Verônica Viana Cardoso; Luiz Fernando de Araújo Ferrão; Rene Felipe Keidel Spada; Orlando Roberto-Neto; Francisco Bolivar Correto Machado


Book ID
112185768
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
431 KB
Volume
112
Category
Article
ISSN
0020-7608

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📜 SIMILAR VOLUMES


Kinetics of the reactions of CH3 with O(
✍ I. C. Plumb; K. R. Ryan 📂 Article 📅 1982 🏛 John Wiley and Sons 🌐 English ⚖ 662 KB

The reactions of CH3 radicals with O(3P) and 0 2 have been studied at 295 K in a gas flow reactor sampled by a mass spectrometer. For the reaction between CH3 and 0, conditions were such that [O] >> [CH3] and the methyl radicals decayed under pseudo-first-order conditions giving a rate coefficient o

Kinetics and mechanism for the reactions
✍ D. Martin; J. L. Jourdain; G. Le Bras 📂 Article 📅 1988 🏛 John Wiley and Sons 🌐 English ⚖ 462 KB 👁 1 views

A kinetic study of the reactions of H atoms with CH,SH and C2H6SH has been carried out at 298 K by the discharge flow technique with EPR and mass spectrometric analysis of the species. The pressure was 1 torr. It was found: k1 = (2.20 \* 0.20) x lo-'' for the reaction H + CH3SH (1) and k2 = (2.40 t

Ab-initio study of the energetics and th
✍ W.C. Kreye 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 497 KB

Ab-initio computations at 298.15 K were made of the activation quantities AH\*, AS\*, and AG\* and of the reaction quantities AH r and AS r for is the transition state (TS). GAUSS-IAN92 was used and energies computed at a slightly modified Gaussian-2 level. Two potential surfaces for the TS had sym