O (3P) + CH3SH reactions: Structures, energetics, and kinetics
✍ Scribed by Daniely Verônica Viana Cardoso; Luiz Fernando de Araújo Ferrão; Rene Felipe Keidel Spada; Orlando Roberto-Neto; Francisco Bolivar Correto Machado
- Book ID
- 112185768
- Publisher
- John Wiley and Sons
- Year
- 2012
- Tongue
- English
- Weight
- 431 KB
- Volume
- 112
- Category
- Article
- ISSN
- 0020-7608
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📜 SIMILAR VOLUMES
The reactions of CH3 radicals with O(3P) and 0 2 have been studied at 295 K in a gas flow reactor sampled by a mass spectrometer. For the reaction between CH3 and 0, conditions were such that [O] >> [CH3] and the methyl radicals decayed under pseudo-first-order conditions giving a rate coefficient o
A kinetic study of the reactions of H atoms with CH,SH and C2H6SH has been carried out at 298 K by the discharge flow technique with EPR and mass spectrometric analysis of the species. The pressure was 1 torr. It was found: k1 = (2.20 \* 0.20) x lo-'' for the reaction H + CH3SH (1) and k2 = (2.40 t
Ab-initio computations at 298.15 K were made of the activation quantities AH\*, AS\*, and AG\* and of the reaction quantities AH r and AS r for is the transition state (TS). GAUSS-IAN92 was used and energies computed at a slightly modified Gaussian-2 level. Two potential surfaces for the TS had sym