Nylon 66 fundamentals and its processes
β Scribed by Ping L. Ku
- Book ID
- 102690496
- Publisher
- John Wiley and Sons
- Year
- 1986
- Tongue
- English
- Weight
- 639 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0730-6679
No coin nor oath required. For personal study only.
β¦ Synopsis
The objective of this paper is to search for and critically examine the pertinent details of the current bulk continuous nylon 66 processes (described in the patents), which are practiced or followed by most nylon producing industries. The two monomers for making nylon 66 and their homologum including dibasic and monobasic acids, diamines, a n d p r i q amines show very interesting melting point behavior. On the other hand, compounds containing even numbers of carbon atoms show consistently higher melting points than the neighboring odd number compounds of higher molecular weights. However, the boiling points of aU four Series follow the usual rule: The higher the molecular weight, the higher the boiling point. It has been proven tlrat the quality of nylon 66 has been greatly improved by lowering the residence time during the polymerization. For instance, the spinning mte employed was at a level of 7000 mlmin, and the tensile strength of the spun yarn was much improved, which was attributed to the overall quality of the polymer.
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## Abstract The chemical changes occurring in nylon (6 and 66) on irradiation have been studied. The results confirm earlier work on model systems which showed the main attack to be between theβNHβgroup of the amide bond and the adjacentβCH~2~βgroup. However, a number of products were found that i