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Nylon 6 polymerization in the solid state

✍ Scribed by Reinoud J. Gaymans; John Amirtharaj; Henk Kamp

Publisher
John Wiley and Sons
Year
1982
Tongue
English
Weight
680 KB
Volume
27
Category
Article
ISSN
0021-8995

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## Abstract Solid‐state polymerization (SSP) of a poly(hexamethyleneadipamide) (PA 6.6)/clay nanocomposite system was studied. SSP runs were performed in a fixed‐bed reactor, at temperatures 160–200 °C and reaction times up to 8 h. The influence of clay presence on the PA 6.6 SSP rate constant was

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An unsteady reaction-diffusion model has been developed to represent the polymerization of a nylon 6,6 prepolymer in a stationary film. A realistic kinetic and equilibrium description is incorporated by the use of apparent rate and equilibrium constants that are composition dependent. The model is s