The classical Stranks-Hush-Marcus theory of pressure effects on the rates of outer-sphere electron transfer reaction rates in solution underestimates IzaV\*[; specifically, for the MnO4/MnO24 (aq) exchange, zaV\*=-21.2 (observed) vs. -6.6cm 3 mol 1 (calculated). This discrepancy can best be resolved
โฆ LIBER โฆ
Numerical solutions of the lamm equation. VI. Effects of hydrostatic pressure on velocity sedimentation of two-component systems
โ Scribed by Dishon, Menachem ;Weiss, George H. ;Yphantis, David A.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1970
- Tongue
- English
- Weight
- 492 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0449-2978
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โฆ Synopsis
Abstract
We present the results of accurate numerical solutions to the Lamm equation, including the effects of hydrostatic pressure, in order to check methods for the estimation of parameters based on a diffusionless theory. Some estimates of boundary spreading due to diffusion are given. The results indicate that parameter estimates based on the position of the maximum concentration gradient lead to fairly accurate results.
๐ SIMILAR VOLUMES
Anomalously large effects of pressure on
โ
T.W. Swaddle; L. Spiccia
๐
Article
๐
1986
๐
Elsevier Science
โ 254 KB