✦ LIBER ✦

Nucleosides of (2r)-2-c-methyl-2-deoxy-erythro-d-pentose

✍ Scribed by J.J.K. Novák; J. Sˇmejkal; F. Sˇorm

Book ID: 104239291
Publisher: Elsevier Science
Year: 1969
Tongue: French
Weight: 92 KB
Volume: 10
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)87964-8

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✦ Synopsis

We wish to report the synthesis of some derivatives of hitherto unknown 2-C-methyl-2-deoxy-erythro-D-pentose with the absolute R configuration at C(2 ). This sugar can be considered as an isoster of D-ribose. The synthesis proceeds from 2-C-methyl-D-ribonolactone (I), which was partially esterified to compound II. This reacted with HBr to give bromo]actone III. Hydrogenolys~s of

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