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Nucleosides. LX. Fluorocarbohydrates. 22. Synthesis of 2-deoxy-2-fluoro-D-arabinose and 9-(2-deoxy-2-fluoro-.alpha. and .beta.-D-arabinofuranosyl)adenines

โœ Scribed by Wright, John Arthur; Taylor, Norman F.; Fox, Jack J.


Book ID
120416730
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
767 KB
Volume
34
Category
Article
ISSN
0022-3263

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โœ Hemant K. Misra; Leonard I. Wiebe; Edward E. Knaus ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› John Wiley and Sons ๐ŸŒ French โš– 422 KB ๐Ÿ‘ 1 views

The reaction of [2-14C]-2 ,4-bis-O-(trimethylsilyl)uracil (2) with ~-~-acetyl-~-0-benzoyl-2-deoxy-2-fluoro-~-D-arabinofuranosyl bromide (3) yielded the 3-O-acety1-5-0-benzoyl nucleos e 4 which was hydrolyzed with methanolic ammonia to afford [ 2-feC]-T-( 2-deoxy-2fluoro-p-D-arabinofuranosy1)uracil (