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Nucleoside anomeric radicals via 1,5-translocation: Facile access to anomeric spiro nucleosides

โœ Scribed by Atsushi Kittaka; Hiromichi Tanaka; Naoki Yamada; Ta-i Miyasaka


Book ID
103411364
Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
220 KB
Volume
37
Category
Article
ISSN
0040-4039

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ChemInform Abstract: 1,5-Translocation S
โœ A. KITTAKA; H. TANAKA; N. YAMADA; H. KATO; T. MIYASAKA ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 32 KB ๐Ÿ‘ 1 views

A new method for generating nucleoside anomeric radicals utilizing radical 1,5translocation is developed. Two kinds of ฮฒ-halovinyl groups at the C6-position of uracil nucleosides are found to be a good radical source. The 5-endo-trig cyclization of the generated nucleoside radicals give spiro nucleo