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Nucleophilic substitution reactions in tetranitrodibenzo-18-crown-6

✍ Scribed by É. I. Ivanov; A. A. Polishchuk; V. E. Kuz'min

Publisher
Springer US
Year
1992
Tongue
English
Weight
193 KB
Volume
28
Category
Article
ISSN
0009-3122

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✦ Synopsis

The nature of the reaction of a reagent with tetranitrodibenzo-18-crown-6 was found to depend on its basicity.

📜 SIMILAR VOLUMES

Synthesis of Substituted Crown-Ethers by
Synthesis of Substituted Crown-Ethers by radical addition of 18-crown-6
✍ Ju. B. Zeleconok; V. V. Orlovskij; Prof. Dr. S. S. Zlotskij; Prof. Dr. D. L. Rac 📂 Article 📅 1990 🏛 John Wiley and Sons 🌐 English ⚖ 238 KB

## Abstract An example of the synthesis of substituted crown‐ethers by radical addition reaction of 18‐crown‐6 (1) to several α‐olefins (2a‐e), cyclohexene (2f), vinyl butyl ether (2g), allyl alcohol (2h), trimethylvinylsilane (2i), diethylmaleate (2j) and formaldehyde (2k) in the presence of a per