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Nucleophilic substitution reactions in chromium arene phosphite dicarbonyl chelate complexes

✍ Scribed by V. V. Krivykh; M. V. Tolstaya; M. I. Rybinskaya

Book ID
112443908
Publisher
Springer
Year
1981
Tongue
English
Weight
178 KB
Volume
30
Category
Article
ISSN
1573-9171

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The Pd-catalyzed reaction of carbanions derived from chromium aminocarbene complexes with allylic acetates and carbonates smoothly affords the corresponding allyl-substituted aminocarbenes. On the contrary, the same reaction of the anion derived from pentacarbonyl[(methoxy)methylcarbene]chromium(0)