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Nucleophilic substitution or dipolar 1,3-cycloaddition in reactions of cyanamide with 4-arylpyrimidine 1-oxides

โœ Scribed by A.M. Prokhorov; D.N. Kozhevnikov; V.L. Rusinov; O.N. Chupakhin

Book ID
111544514
Publisher
Springer
Year
2003
Tongue
English
Weight
252 KB
Volume
52
Category
Article
ISSN
1573-9171

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โœ Ronald Grigg; Jasothara Markandu ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 195 KB

Regiospecific nucleophilic substitution reactions involving attack of the nitrogen atom of oximes on epoxides are used to generate nitrones which are then trapped in 1,3-dipolar cycloaddition reactions. These tandem processes are shown to be flexible and to have wide synthetic scope for the construc