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Nucleophilic substitution on arylazo compounds: part IV. reactions of chloro-substituted arylazonaphthalenes with primary and secondary amines

✍ Scribed by Horst Hartmann; Margit Schulze; Ralf Guenther


Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
856 KB
Volume
16
Category
Article
ISSN
0143-7208

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Cyclometalation of Arylazo Compounds. Pa
✍ Alfred J. Klaus; Paul Rys 📂 Article 📅 1981 🏛 John Wiley and Sons 🌐 German ⚖ 958 KB

## Abstract The syntheses of 1‐phenylazonaphthalene (**1a**) and its [3′‐methyl‐ (**1b**), 4′‐methoxy‐ (**1c**), 3′‐methoxy‐ (**1d**)] derivatives are described. Cyclopalladation of these azo ligands with Pd(II) acetate or Na~2~PdCl~4~ leads to complexes with Pd(II) coordinated on the azo N~β~‐atom