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Nucleophilic substitution of hydrogen (9-H) in acridinium salts by phenols

โœ Scribed by O. N. Chupakhin; V. I. Shilov; I. Ya. Postovskii; V. A. Trofimov


Book ID
112362081
Publisher
Springer US
Year
1976
Tongue
English
Weight
502 KB
Volume
12
Category
Article
ISSN
0009-3122

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Oxidative nucleophilic substitution of h
โœ Mieczysล‚aw Mฤ…kosza; Marek Surowiec ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 158 KB

Enolates generated by treatment of silyl ketene acetals and enol ethers with fluoride ion sources add to nitroarenes to produce s H adducts that oxidize either with KMnO 4 to give substituted nitroarenes or with dimethyldioxirane to give substituted phenols. In the latter case the oxidation results