Nucleophilic Substitution of Bis(cyclopentadienyl)-tin(II); Synthesis, Structure, and Solution Dynamics of trans-[(η3-Cp)Sn{μ2-NC(NMe2)2}]2

Synthesis, Structure, Electrochemistry a

Synthesis, Structure, Electrochemistry and Reactivity of the Bis(μ-σ-stannanediyl)dinickel Butterfly Cluster [{{(SiMe3)2CH}2Sn–Ni(η5-Cp)}2](Ni2–Sn2)

✍ Jörg J. Schneider; Jörg Hagen; Dieter Bläser; Roland Boese; Fabrizia Fabrizi de 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 402 KB

Addition of stannylene [{(SiMe 3 ) 2 CH} 2 Sn:] (2) to the unbridged water results in the cleavage of an Ni-Sn bond and subsequent opening of the cluster cage of 3 to form the trinuclear homobimetallic Ni-Ni bond of [{PEt 3 Ni(η 5 -Cp)} 2 ] (1) gives the heterobimetallic, tetranuclear compound [{{(S