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Nucleophilic substitution in fluoroolefins. I Reactions of amines with alkoxyfluorocycloolefins

✍ Scribed by Fred Dreier; Warren Duncan; Theodore Mill

Publisher
Elsevier Science
Year
1964
Tongue
French
Weight
174 KB
Volume
5
Category
Article
ISSN
0040-4039

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✦ Synopsis

Primary and secondary amines react rapidly with perfluoro-and halofluoroolefins to give aminofluoroalkanes and fluorovinylamines by addition and additiou-elimination reactions.' We report here on the reaction of se"-era1 alkoxyfluorocycloolefins with primary and secondary amines to give alkylamino-unsaturated cyclic ketones.

1-Methoxy-2-chlorohexafluorocyclopentene (I) reacts rapidly and smoothly at 25O with primary and secondary amines to give the corresponding l-alkyl-

πŸ“œ SIMILAR VOLUMES

Nucleophilic heteroaromatic substitution
Nucleophilic heteroaromatic substitution: Kinetics of the reactions of nitropyridines with aliphatic amines in dipolar aprotic solvents
✍ Chukwuemeka Isanbor; Thomas A. Emokpae πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 256 KB

## Abstract Rate data are reported for the reactions of 2‐chloro‐5‐nitropyridine **2a**, 2‐chloro‐3‐nitropyridine **2b**, and the corresponding 2‐phenoxy derivatives **2c** with __n__‐butylamine, pyrrolidine and piperidine and **2d** with __n__‐butylamine and pyrrolidine in dimethyl sulfoxide (DMSO